J. Debritto et al., DETERMINATION OF AGLYCONE CHIRALITY IN DIHYDROFLAVONOL 3-O-ALPHA-1-RHAMNOSIDES BY H-1-NMR SPECTROSCOPY, Chemical and Pharmaceutical Bulletin, 43(2), 1995, pp. 338-339
Three dihydroflavonol glycosides, 3-O-alpha-L-rhamnosides of (2S,3S)-,
(2R,3R)- and (2R,3S)-5,7,3',4'tetrahydroxydihydroflavonol, were isola
ted from Sphaerostephanos arbuscula as the first example of dihydrofla
vonols from ferns, Aglycone chirality was determined by H-1-NMR data.