Yn. Demkov et Vn. Ostrovsky, CROSSING OF 2 BANDS OF POTENTIAL CURVES, Journal of physics. B, Atomic molecular and optical physics, 28(3), 1995, pp. 403-414
Various problems in atomic physics can be formulated in terms of two b
ands of potential curves which cross each other. Each band consists of
parallel (non-interacting) diabatic potential curves equally spaced o
n the energy axis. The bands with infinite number of states are consid
ered under the assumption of 'translational' symmetry along the energy
axis. The adiabatic potential curves are constructed explicitly. The
system of avoided crossings appears not only in the weak coupling case
(which is obvious), but also in the strong coupling limit. This featu
re also holds in the generalized model where the bands are finite and
non-equidistant. In the case of an infinite number of states in each b
and the dynamic description (i.e. evolution in time) is reduced to the
two-state problem which contains an additional continuous parameter (
analogue of the quasimomentum). Some peculiarities of the time propaga
tion are discussed. The present model generalizes the famous Landau-Ze
ner two-state case and Demkov-Osherov model (one level interacting wit
h a band of levels).