Photochemical properties of a diarylethene with a thiophene and a benz
othiophene ring in Langmuir-Blodgett (LB) films have been examined. Th
e diarylethene, which exhibited a highly effective photochromism in fl
uid solution, was found to show a similar photochromism in LB films. T
he quantum yields of coloring and breaching reactions have been determ
ined to be 0.27 and 0.10, respectively.