1ST SYNTHESIS OF CHIRAL 3-VINYLINDOLES AS 4-PI-COMPONENTS FOR DIELS-ALDER REACTIONS
Citation
U. Pindur et al., 1ST SYNTHESIS OF CHIRAL 3-VINYLINDOLES AS 4-PI-COMPONENTS FOR DIELS-ALDER REACTIONS, Journal of heterocyclic chemistry, 32(1), 1995, pp. 201-206
Categorie Soggetti
Chemistry Inorganic & Nuclear
SICI code
0022-152X(1995)32:1<201:1SOC3A>2.0.ZU;2-O
Abstract
The first syntheses of chiral 3- and 2-vinylindoles bearing sulfoxide
or (-)-menthyloxy functional groups at the beta-vinyl positions by way
of procedures based on the Horner-Wadsworth-Emmons and Wittig reactio
ns, respectively, are described. Some Diels-Alder reactions the 4 pi-r
eactivity of these compounds are reported.