AN UNEQUIVOCAL SYNTHESIS OF THE RING-A,B DIHYDROPYRROMETHENONE OF PHYTOCHROME

Citation
Pa. Jacobi et al., AN UNEQUIVOCAL SYNTHESIS OF THE RING-A,B DIHYDROPYRROMETHENONE OF PHYTOCHROME, Tetrahedron letters, 36(8), 1995, pp. 1197-1200
Citations number
35
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
36
Issue
8
Year of publication
1995
Pages
1197 - 1200
Database
ISI
SICI code
0040-4039(1995)36:8<1197:AUSOTR>2.0.ZU;2-O
Abstract
Dihydropyrromethenone 1b (R = p-methoxybenzyl), a potential precursor for the synthesis of phytochrome (3), has been prepared in enantiomeri cally pure form beginning with the homochiral acetylenic lactone 18.