Questions about trace metal preservation are resurfacing because the h
ealth effect risks associated with certain metals continue to drive th
e required reporting limits lower. Inductively coupled plasma-mass spe
ctrometry was used in this study to analyze preservation of samples co
ntaining trace metals. Metal concentrations in nonacidified drinking w
aters may decrease if the sample is held for two weeks. Acidification
of these drinking water samples resolubilized the metals that had fall
en out of solution. The preservation of metal samples within drinking
waters by acidification to a pH of <2 effectively stabilized the metal
concentration for 180 days.