Piezoelectricity is usually expressed as an interaction between mechan
ical and electrical variables. The physics involved is hence governed
by a coupling between Maxwell's equations of electromagnetism and the
equations of elasticity. Such a coupling takes us through the piezoele
ctric constitutive relations. In this work, the second order anisotrop
ic constitutive equations are treated, and, in particular, the number
of independent material constants is computed for all the 32 crystallo
graphic classes.