REGIOSELECTIVE AND STEREOSELECTIVE CYCLOA DDITIONS OF NITRONES AND ALPHA,BETA-UNSATURATED GAMMA-LACTAMS

Citation
N. Langlois et al., REGIOSELECTIVE AND STEREOSELECTIVE CYCLOA DDITIONS OF NITRONES AND ALPHA,BETA-UNSATURATED GAMMA-LACTAMS, Comptes rendus de l'Academie des sciences. Serie II. Mecanique, physique, chimie, astronomie, 320(3), 1995, pp. 155-158
Citations number
17
Categorie Soggetti
Multidisciplinary Sciences
ISSN journal
12518069
Volume
320
Issue
3
Year of publication
1995
Part
1
Pages
155 - 158
Database
ISI
SICI code
1251-8069(1995)320:3<155:RASCDO>2.0.ZU;2-I
Abstract
alpha, beta-Unsaturated gamma-lactams 2 and 3 undergo regio- and stere oselective 1,3-dipolar cycloadditions with N-benzyl- and N-methyl nitr ones and can act as acceptors in conjugate addition of N-methylhydroxy lamine. These reactions give access to highly functionalized pyrrolido nes.