Sd. Pollington et al., A HIGH-POWER X-BAND PULSED MICROWAVE-INDUCED CATALYTIC DECOMPOSITION OF METHANE WITH INTEGRAL ACOUSTIC MEASUREMENTS, Research of chemical intermediates, 21(1), 1995, pp. 59-68
A high-power microsecond pulsed microwave system operating in the X-ba
nd region was used for the catalytic conversion of methane. Microwave
microsecond pulses at repetition rates of 50 and 80 Hz were used to in
itiate chemical reactions. The Microwave-Induced Acoustic technique wa
s employed in combination with gas chromatography for on-line detectio
n of chemical products. Methane was converted to C-2 and C-3 hydrocarb
ons. The selectivity of ethane in hydrocarbon products can be >90 %. T
he contribution of hydrogen evolution and carbon deposition has been s
hown to be important. A comparison between previous experiments perfor
med with millisecond pulse durations is given.