A HIGH-POWER X-BAND PULSED MICROWAVE-INDUCED CATALYTIC DECOMPOSITION OF METHANE WITH INTEGRAL ACOUSTIC MEASUREMENTS

Citation
Sd. Pollington et al., A HIGH-POWER X-BAND PULSED MICROWAVE-INDUCED CATALYTIC DECOMPOSITION OF METHANE WITH INTEGRAL ACOUSTIC MEASUREMENTS, Research of chemical intermediates, 21(1), 1995, pp. 59-68
Citations number
17
Categorie Soggetti
Chemistry
ISSN journal
09226168
Volume
21
Issue
1
Year of publication
1995
Pages
59 - 68
Database
ISI
SICI code
0922-6168(1995)21:1<59:AHXPMC>2.0.ZU;2-0
Abstract
A high-power microsecond pulsed microwave system operating in the X-ba nd region was used for the catalytic conversion of methane. Microwave microsecond pulses at repetition rates of 50 and 80 Hz were used to in itiate chemical reactions. The Microwave-Induced Acoustic technique wa s employed in combination with gas chromatography for on-line detectio n of chemical products. Methane was converted to C-2 and C-3 hydrocarb ons. The selectivity of ethane in hydrocarbon products can be >90 %. T he contribution of hydrogen evolution and carbon deposition has been s hown to be important. A comparison between previous experiments perfor med with millisecond pulse durations is given.