INFRARED STUDY OF 4-X BENZOIC-ACIDS IN CCL4 AND OR CHCL3 SOLUTIONS/

Authors
NYQUIST RA CLARK TD
Citation
Ra. Nyquist et Td. Clark, INFRARED STUDY OF 4-X BENZOIC-ACIDS IN CCL4 AND OR CHCL3 SOLUTIONS/, Vibrational spectroscopy, 8(3), 1995, pp. 387-400
Citations number
40
Categorie Soggetti
Spectroscopy,"Chemistry Analytical","Chemistry Physical
Journal title
Vibrational spectroscopy → ACNP
ISSN journal
09242031
Volume
8
Issue
3
Year of publication
1995
Pages
387 - 400
Database
ISI
SICI code
0924-2031(1995)8:3<387:ISO4BI>2.0.ZU;2-7
Abstract
The upsilon(C double bond O) and upsilon(op)(C double bond O)(2) modes for 4-x benzoic acids in CHCl3 and/or CCl4 solutions decrease in freq uency as the sigma(p) values for the 4-x atoms or groups decrease in v alue while the upsilon(OH) mode increases in frequency. Different comp lexes are formed between the CO2H and (CO2H)(2) groups as the mole% CH Cl3/CCl4 changes from 0 to 100.