3RD-ORDER NLO PROPERTIES OF METAL-COMPLEXES CONTAINING DELOCALIZED NITROGEN DONOR LIGANDS

Authors
DHINDSA AS UNDERHILL AE OLIVER S KERSHAW S
Citation
As. Dhindsa et al., 3RD-ORDER NLO PROPERTIES OF METAL-COMPLEXES CONTAINING DELOCALIZED NITROGEN DONOR LIGANDS, Journal of materials chemistry, 5(2), 1995, pp. 261-264
Citations number
14
Categorie Soggetti
Chemistry Physical","Material Science
Journal title
Journal of materials chemistry → ACNP
ISSN journal
09599428
Volume
5
Issue
2
Year of publication
1995
Pages
261 - 264
Database
ISI
SICI code
0959-9428(1995)5:2<261:3NPOMC>2.0.ZU;2-L
Abstract
Complexes of 3,4-toluenediamine, [M(tdi)(2)] where M=Ni, Pd or Pt, and 3,4-benzophenonediamine, [Ni(bpdi)(2)], have been synthesized and the value of chi((3)) has been determined in DMSO at 1064 nm by the retro reflection DFWM technique. A value for chi((3)) Of 10.3 X 10(-13) esu was observed for [Ni(bpdi)(2)] with a ratio of chi(xxxx)(3)/chi(xyyx)( (3)) of 3, suggesting a non-linear process that is predominantly elect ronic.