G. Aka et al., OPTICAL-PROPERTIES OF SINGLE-CRYSTALS OF GALLIUM-SUBSTITUTED NYAB - Y1-XNDX(AL1-XGAY)(3)(BO3)(4), Journal of materials chemistry, 5(2), 1995, pp. 265-271
Flux-grown single crystals of non-linear neodymium-doped yttrium alumi
nium tetraborate (NYAB), substituted with gallium (NYAB-Ga), have been
prepared. The Judd-Ofelt theory has been applied to evaluate the inte
nsity parameters (Omega(2),Omega(4),Omega(6)), radiative transition ra
tes and branching ratios. The optical behaviour of NYAB-Ga crystals, c
ontaining 0.3 Ga has been investigated. The emission cross-sections fo
r the F-4(3/2)-->I-4(11/2) transition in Nd3+ have been calculated and
compared with those in NYAB, with a view to developing new self-frequ
ency-doubling materials.