G. Wojcik et al., CRYSTAL-STRUCTURES, PHASE-TRANSITIONS, AND HYDROGEN BONDINGS IN PENTABROMOPHENOL, PENTACHLOROPHENOL, AND THEIR MIXED-CRYSTALS, Physica status solidi. a, Applied research, 147(1), 1995, pp. 99-109
Pure pentachlorophenol, pentabromophenol, and their mixed crystal cont
aining 12 mol% of pentabromophenol are studied by differential scannin
g calorimetry (DSC), X-ray diffraction, and near-IR spectroscopy. The
resolved crystal structure of pentabromophenol is P2(1) with a = 0.823
8(8) nm, b = 0.4021(9) nm, c = 1.4822(8) nm, beta = 95.82(6)-degrees,
Z = 2. The mixed crystal is isostructural with pentachlorophenol. Temp
eratures and enthalpies of phase transitions occurring in the studied
crystals above room temperature are measured. Inter- and intramolecula
r hydrogen bondings and free OH groups are monitored by the overtone b
and of the OH stretching vibration measured as a function of temperatu
re and time. The metastable phase occurrence is also studied with X-ra
y powder diffraction and dilatometry.