The excimer laser ablation of neodymium (Nd) doped glass and Nd doped
yttrium aluminium garnet (YAG) crystals has been performed using 193 a
nd 248 nm radiation. Etch rate versus fluence (energy per unit area) p
lots show that the ablation thresholds are in the range 0.5-1.6 J/cm(2
). The effective absorption coefficients thus measured were found to b
e of the order of 10(4)-10(5) cm(-1), two or three orders of magnitude
greater than the small signal absorption coefficient. The ablation of
Nd:YAG and Nd:grass at 193 nm produced etch pits of superior quality
to those pits produced using 248 nm laser exposure. Time integrated em
ission spectra of the ablated plumes in vacuum showed up to one hundre
d lines for Nd:YAG at both wavelengths while the Nd:glass spectra were
simpler, considerably so for 248 nm irradiation.