THE ACIDITY SCALE OF HCL SOLUTIONS IN N,N-DIMETHYLFORMAMIDE

Authors
KISLINA IS SYSOEVA SG TEMKIN ON
Citation
Is. Kislina et al., THE ACIDITY SCALE OF HCL SOLUTIONS IN N,N-DIMETHYLFORMAMIDE, Russian chemical bulletin, 43(6), 1994, pp. 960-963
Citations number
7
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
43
Issue
6
Year of publication
1994
Pages
960 - 963
Database
ISI
SICI code
1066-5285(1994)43:6<960:TASOHS>2.0.ZU;2-7
Abstract
The scale of the thermodynamic acidity of HCl solutions in DMF has bee n measured at 25 and 39.5 degrees C up to 15 mol L(-1) acid concentrat ion by the indicator method. It is shown that in the HCl-DMF system th e ionization of the nitroaniline-derived indicators occurs by the ion pair mechanism. Within the temperature range studied acidity is indepe ndent of temperature. Indicator; of the nitroaniline series are used.