SYNTHESIS OF POLYFLUORINATED KETONES VIA THE ATE-COMPLEXES

Authors
PASHKEVICH KI KHOMUTOV OG FILYAKOVA VI KUCHIN AV
Citation
Ki. Pashkevich et al., SYNTHESIS OF POLYFLUORINATED KETONES VIA THE ATE-COMPLEXES, Russian chemical bulletin, 43(6), 1994, pp. 1002-1003
Citations number
3
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
43
Issue
6
Year of publication
1994
Pages
1002 - 1003
Database
ISI
SICI code
1066-5285(1994)43:6<1002:SOPKVT>2.0.ZU;2-R
Abstract
Asymmetric polyfluorinated ketones R(F)COR are formed by treating vari ous derivatives of (polyfluoro)alkanoic acids (esters, anhydrides, aci d chlorides) with lithium tetraalkylaluminates (''ate-complexes''). Th e highest yields of the ketones (65-78 %) were obtained from (polyfluo ro)alkanoyl chlorides.