K. Matsuyama et al., SALT EFFECT OF POTASSIUM ACETATE ON VAPOR -LIQUID-EQUILIBRIA OF ETHANOL-WATER AND METHANOL-ETHANOL SYSTEMS, Kagaku kogaku ronbunshu, 21(1), 1995, pp. 230-233
The activities of methanol, ethanol or water in potassium acetate solu
tions and the vapor-liquid equilibrium relations of methanol-ethanol-p
otassium acetate and ethanol-water-potassium acetate systems were dete
rmined by use of a flow-type apparatus at 298.15 K. The activity data
are presented for single solvent and vapor-liquid equilibrium data are
shown for mixed solvents. Salting-out and salting-in effects of potas
sium acetate were shown for ethanol-water and methanol-ethanol systems
, respectively. Further, the experimental data were correlated by usin
g the model of Chen et al.