NOVEL SYNTHESIS OF ALKYLIDYNETRINICKEL CLUSTERS

Citation
S. Pasynkiewicz et al., NOVEL SYNTHESIS OF ALKYLIDYNETRINICKEL CLUSTERS, Journal of organometallic chemistry, 489(1-2), 1995, pp. 48-49
Citations number
6
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
ISSN journal
0022328X
Volume
489
Issue
1-2
Year of publication
1995
Pages
48 - 49
Database
ISI
SICI code
0022-328X(1995)489:1-2<48:NSOAC>2.0.ZU;2-O
Abstract
Nickelocene re acts with phenyllithium in the presence of terminal ole fins to form ta(5)-cyclopentadienyl)(mu(3)-alkylidyne)trinickel cluste rs (NiCp)(3)CR. It is a new, simple method for the synthesis of (mu(3) -alkylidyne)trinickel clusters with various R groups.