ARENE RUTHENIUM(II) COMPLEXES COORDINATED BY PHOSPHINO AND 2 PHENOXIDE GROUPS IN TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE - CRYSTAL-STRUCTURE OF H(2))RU[P(2,6-(MEO)(2)C6H3)(2-O-6-MEOC(6)H(3))(2)]

Authors
YAMAMOTO Y SATO R OHSHIMA M MATSUO F SUDOH C
Citation
Y. Yamamoto et al., ARENE RUTHENIUM(II) COMPLEXES COORDINATED BY PHOSPHINO AND 2 PHENOXIDE GROUPS IN TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE - CRYSTAL-STRUCTURE OF H(2))RU[P(2,6-(MEO)(2)C6H3)(2-O-6-MEOC(6)H(3))(2)], Journal of organometallic chemistry, 489(1-2), 1995, pp. 68-70
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
489
Issue
1-2
Year of publication
1995
Pages
68 - 70
Database
ISI
SICI code
0022-328X(1995)489:1-2<68:ARCCBP>2.0.ZU;2-Y
Abstract
The title compound has been prepared from bis[dichloro(eta(6)-arene)ru thenium] (eta(6)-arene = 1,2,3,4-C(6)Me(4)H(2) (1a), p-cymene (1b) and tris(2,6-dimethoxyphenyl)phospine (TDMPP). The crystal structure feat ures a type of eta(3)-phosphino-two phenoxides coordination. Reactions with its related phosphines, bis(2,6-dimethoxyphenyl)phenylphosphine (BDMPP) and (2,6-dimethoxyphenyl)diphenylphosphine (MDMPP) gave comple xes with eta(2)-phosphino-phenoxide and eta(1)-phosphino coordinations , and trans-RuCl2(MDMPP)(2), depending on phosphines and arene groups.