SYNTHESIS OF SANDWICH AND HALF-SANDWICH COMPLEXES OF TI, ZR AND HF CONTAINING ETA(5)-C(5)H(4)SIME(2)CL LIGAND - MOLECULAR-STRUCTURE OF [TICL2(MU-OSIME(2)-ETA(5)-C5H4)](2)

Authors
CHURAKOV AV LEMENOVSKII DA KUZMINA LG
Citation
Av. Churakov et al., SYNTHESIS OF SANDWICH AND HALF-SANDWICH COMPLEXES OF TI, ZR AND HF CONTAINING ETA(5)-C(5)H(4)SIME(2)CL LIGAND - MOLECULAR-STRUCTURE OF [TICL2(MU-OSIME(2)-ETA(5)-C5H4)](2), Journal of organometallic chemistry, 489(1-2), 1995, pp. 81-83
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
489
Issue
1-2
Year of publication
1995
Pages
81 - 83
Database
ISI
SICI code
0022-328X(1995)489:1-2<81:SOSAHC>2.0.ZU;2-C
Abstract
Reactions of (C(5)H(4)SiMe(3))SiMe(2)Cl (1) and (mu-SiMe(2)C(5)H(4))(2 ) (2) with Ti, Zr and Hf tetrachlorides lead to the complexes M(eta(5) -C(5)H(4)SiMe(2)Cl)Cl-3 (M = Ti, 3a; Zr, 3b; Hf, 3c). Treatment of 3a with cyclopentadienyl thallium affords Ti(eta(5)-C5H5)(eta(5)- C(5)H(4 )SiMe(2)Cl)Cl-2 (4). Dimeric oxo-derivative [TiCl2(mu-OSiMe(2)-eta(5)- C5H4)](2) (5) was prepared by slow hydrolysis of 3a. Structure of 5 wa s determined by X-ray diffraction.