[(C5H5)FE(C(5)H(4)CH(2)NME(2))] AS A PROMOTER FOR THE SYNTHESIS OF THE 1,2-DISUBSTITUTED FERROCENYL ALDEHYDES [(C5H5)FE(1,2-C5H3(CHO)(CH(2)NME2)] AND [(C5H5)FE(1,2-C5H3(CHO)CH(2)NME(CH2)(2)OCH=CH2)]

Authors
DELAVAUXNICOT B GUARI Y MATHIEU R
Citation
B. Delavauxnicot et al., [(C5H5)FE(C(5)H(4)CH(2)NME(2))] AS A PROMOTER FOR THE SYNTHESIS OF THE 1,2-DISUBSTITUTED FERROCENYL ALDEHYDES [(C5H5)FE(1,2-C5H3(CHO)(CH(2)NME2)] AND [(C5H5)FE(1,2-C5H3(CHO)CH(2)NME(CH2)(2)OCH=CH2)], Journal of organometallic chemistry, 489(1-2), 1995, pp. 87-89
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
489
Issue
1-2
Year of publication
1995
Pages
87 - 89
Database
ISI
SICI code
0022-328X(1995)489:1-2<87:[AAPFT>2.0.ZU;2-0
Abstract
The one pot synthesis of [(C5H5)Fe(1,2-C5H3(CHO)(CH(2)NMe(2))}] (2) fr om [(C5H5)Fe(C(5)H(4)CH(2)NMe(2))] (1) is described. The new biferroce nyl compound [{(C5H5)FeC(5)H(4)CH(2)ONMe(CH2)(2)OCH2}(2)] (3), whose p reparation is reported, reacts successively with 2 mole equivalents of LiBu and DMF (-78 degrees C) to give, among other products, the aldeh yde [(C5H5)Fe(1,2-C5H3(CHO)CH(2)NMe(CH2)(2)OCH=CH2}] (6).