SUBSTRATE MISORIENTATION, MULTI-QUANTUM-BARRIER, AND THERMAL ANNEALING EFFECTS IN MGZNSSE AND ZNCDSE COMPOUNDS AND BLUE-GREEN II-VI LIGHT-EMITTING DEVICES
K. Kishino et al., SUBSTRATE MISORIENTATION, MULTI-QUANTUM-BARRIER, AND THERMAL ANNEALING EFFECTS IN MGZNSSE AND ZNCDSE COMPOUNDS AND BLUE-GREEN II-VI LIGHT-EMITTING DEVICES, Physica status solidi. b, Basic research, 187(2), 1995, pp. 327-335
Multi-quantum-barrier (MQB), substrate misorientation, and thermal ann
ealing effects are investigated in MgZnSSe and ZnCdSe compounds and bl
ue-green II-VI light emitting devices. The heterobarrier enhancement o
f MgZnSSe/ZnSe MQBs is analyzed to be 100 meV, using the experimental
band offset of Delta E(c) approximate to 0.65 Delta E(g). By use of MQ
B effect, low threshold current density operation below 1 kA/cm(2) can
be expected in 480 nm blue emission ZnCdSe/MgZnSSe lasers. For N-dope
d MgZnSSe grown on intentionally misoriented GaAs substrates, the decr
eased net acceptor concentration with misorientation angle is discusse
d, concluding that the enhanced sulfur incorporation by substrate miso
rientation plays some role in degradation. It is clarified that ZnSe a
nd ZnSSe are not degraded up to 400 degrees C annealing, while MgZnSSe
is even at 350 to 400 degrees C annealing. The light output of ZnCdSe
/ZnSe MQW LEDs is enhanced by thermal annealing (325 degrees C, 7 min)
, by a factor of three.