PREPARATION AND CRYSTAL-STRUCTURE OF A NEW FAMILY OF TRANSITION-METALPHOSPHO-SILICIDES

Citation
C. Perrier et al., PREPARATION AND CRYSTAL-STRUCTURE OF A NEW FAMILY OF TRANSITION-METALPHOSPHO-SILICIDES, Materials research bulletin, 30(3), 1995, pp. 357-364
Citations number
10
Categorie Soggetti
Material Science
Journal title
ISSN journal
00255408
Volume
30
Issue
3
Year of publication
1995
Pages
357 - 364
Database
ISI
SICI code
0025-5408(1995)30:3<357:PACOAN>2.0.ZU;2-A
Abstract
Single crystals of new high phosphorus-silicon content compounds of tr ansition metal FeSi4P4, RuSi4P4 and OsSi4P4 have been obtained from ti n flux. Powders of the same composition have been prepared by reaction of the elemental components in evacuated silica tubes. These compound s are isomorphic. Crystal structure of FeSi4P4 and RuSi4P4 have been d etermined from four-circle diffractometer data of single crystals.