ON THE KNOWLEDGE OF 2 THALLIUM-TELLUROCHROMITES [TLCRTE2 AND TLCR5TE8]

Authors
BOLLER H KLEPP KO KIRCHMAYR K
Citation
H. Boller et al., ON THE KNOWLEDGE OF 2 THALLIUM-TELLUROCHROMITES [TLCRTE2 AND TLCR5TE8], Materials research bulletin, 30(3), 1995, pp. 365-371
Citations number
8
Categorie Soggetti
Material Science
Journal title
Materials research bulletin → ACNP
ISSN journal
00255408
Volume
30
Issue
3
Year of publication
1995
Pages
365 - 371
Database
ISI
SICI code
0025-5408(1995)30:3<365:OTKO2T>2.0.ZU;2-9
Abstract
The title compounds were prepared and their crystal structures determi ned. TlCrTe2 is hexagonal (a = 4.016 Angstrom, c = 7.927 Angstrom) hav ing a CdI2 derived pseudo-intercalation structure. The single crystal refinement of TlCr5Te8 (monoclinic TlV5S8 type, a = 20.241 Angstrom, b = 3.9141 Angstrom, c = 9.481 Angstrom, beta = 104.65 degrees) reveale d a disorder of thallium in a split position within the channels of th e [Cr5Te8] framework.