Cg. Zheng et A. Borysow, ROTOTRANSLATIONAL COLLISION-INDUCED ABSORPTION BY H-2-H-2 PAIRS AT TEMPERATURES FROM 600-K TO 7000-K, The Astrophysical journal, 441(2), 1995, pp. 960-965
The computation of the far-infrared, rototranslational (RT) collision-
induced absorption (CIA) spectra of H-2-H-2 pairs is presented at temp
eratures from 600 to 7000 K for the first time. Theoretical results ar
e based on the quantum mechanical and the semiclassical, three lowest
translational spectral moments obtained for H-2 pairs. The effective,
isotropic H-2-H-2 interaction potential, suitable for the high-tempera
ture computations, and the ab initio induced dipoles, have been used a
s input. Special effort has been made to account for the rotational an
d vibrational states dependence of the dipoles, since it was found to
be relevant at the high temperatures employed. The computations of the
entire RT band account for all populated vibrational states of hydrog
en molecule and include vibrational transitions upsilon --> upsilon' =
upsilon, with upsilon = 0, 1, 2, and 3. The described method makes us
e of the adequately selected model line shapes with the temperature-de
pendent parameters. The presented model is useful for the ''model atmo
spheres'' of zero- and low-metallicity, cool and dense stellar atmosph
eres, where CIA is known to be important.