ISOBARIC VAPOR-LIQUID-EQUILIBRIA IN THE BINARY-SYSTEMS OF 1,3-DIOXOLANE, 1-CHLOROBUTANE AND 2-CHLOROBUTANE

Authors
WISNIAK J APELBLAT A ZABICKY J FEINGOLD I
Citation
J. Wisniak et al., ISOBARIC VAPOR-LIQUID-EQUILIBRIA IN THE BINARY-SYSTEMS OF 1,3-DIOXOLANE, 1-CHLOROBUTANE AND 2-CHLOROBUTANE, Physics and chemistry of liquids, 28(3), 1994, pp. 177-185
Citations number
10
Categorie Soggetti
Chemistry Physical","Physics, Condensed Matter
Journal title
Physics and chemistry of liquids → ACNP
ISSN journal
00319104
Volume
28
Issue
3
Year of publication
1994
Pages
177 - 185
Database
ISI
SICI code
0031-9104(1994)28:3<177:IVITBO>2.0.ZU;2-3
Abstract
Vapor-liquid equilibrium at 101.3 kPa has been determined for the bina ry systems of 1,3-dioxolane, 1-chlorobutane and 2-chlorobutane. The bi nary systems 1,3-dioxolane-chlorobutanes exhibit positive deviations f rom ideal behavior while the binary 1-chlorobutane-2-chlorobutane beha ves ideally. The activity coefficients and boiling point of the soluti on were correlated with its composition by the Redlich-Kister and Wisn iak-Tamir equations.