FACTORS AFFECTING CHELATION OF CARBOXYLATES TO CIS-DIAQUA CO(III) COMPLEXES - IMPLICATIONS ON THE REACTIVITY OF THE METAL-COMPLEXES FOR HYDROLYZING ESTERS, AMIDES, NITRILES, AND PHOSPHATES

Authors
CONNOLLY JA KIM JH BANASZCZYK M DROUIN M CHIN J
Citation
Ja. Connolly et al., FACTORS AFFECTING CHELATION OF CARBOXYLATES TO CIS-DIAQUA CO(III) COMPLEXES - IMPLICATIONS ON THE REACTIVITY OF THE METAL-COMPLEXES FOR HYDROLYZING ESTERS, AMIDES, NITRILES, AND PHOSPHATES, Inorganic chemistry, 34(5), 1995, pp. 1094-1099
Citations number
39
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
34
Issue
5
Year of publication
1995
Pages
1094 - 1099
Database
ISI
SICI code
0020-1669(1995)34:5<1094:FACOCT>2.0.ZU;2-2
Abstract
The equilibrium constant for chelation of carboxylates to cis-diaqua t etraamine Co(III) complexes is highly sensitive to the tetraamine liga nd structure, basicity of the chelating carboxylate, and solvent polar ity. cis-Diaqua tetraamine Co(III) complexes that easily accommodate c helation of carboxylates are also highly reactive for hydrolyzing carb oxyl esters, amides, nitriles, and phosphate esters. The X-ray crystal strcuture of [(trpn)Co(eta(2)-O2CC(CH3)(3)]-(ClO4)(2) has been determ ined: trpn = tris(3-aminopropyl)amine, C14H33N4O10Cl2CO, orthorhombic, P2(1)2(1)2(1), a = 8.7822(3)Angstrom, b = 14.9959(6)Angstrom, c = 17. 5277(5)Angstrom, V = 2308.35(14) Angstrom(3), Z = 4.