DIASTEREOSELECTIVE REDUCTIONS OF BETA-SUBSTITUTED-GAMMA-KETO SULFOXIMINES AND A NOVEL PALLADIUM(0)-CATALYZED ALLYLIC SULFOXIMINE TO ALLYLICSULFINAMIDE REARRANGEMENT

Authors
PYNE SG DONG ZM SKELTON BW WHITE AH
Citation
Sg. Pyne et al., DIASTEREOSELECTIVE REDUCTIONS OF BETA-SUBSTITUTED-GAMMA-KETO SULFOXIMINES AND A NOVEL PALLADIUM(0)-CATALYZED ALLYLIC SULFOXIMINE TO ALLYLICSULFINAMIDE REARRANGEMENT, Journal of the Chemical Society, Chemical Communications, (4), 1995, pp. 445-446
Citations number
16
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
4
Year of publication
1995
Pages
445 - 446
Database
ISI
SICI code
0022-4936(1995):4<445:DROBS>2.0.ZU;2-E
Abstract
The reduction of beta-substituted-gamma-keto N-tosyl sulfoximines is h ighly diastereoselective and the allylic sulfoximines products undergo a facile rearrangement to allylic sulfinamides in the presence of a p alladium(0) catalyst.