FUNCTIONALIZATION OF [MO6O19](2-) WITH AROMATIC-AMINES - SYNTHESIS AND STRUCTURE OF A HEXAMOLYBDATE BUILDING-BLOCK WITH LINEAR DIFUNCTIONALITY

Authors
CLEGG W ERRINGTON RJ FRASER KA HOLMES SA SCHAFER A
Citation
W. Clegg et al., FUNCTIONALIZATION OF [MO6O19](2-) WITH AROMATIC-AMINES - SYNTHESIS AND STRUCTURE OF A HEXAMOLYBDATE BUILDING-BLOCK WITH LINEAR DIFUNCTIONALITY, Journal of the Chemical Society, Chemical Communications, (4), 1995, pp. 455-456
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
4
Year of publication
1995
Pages
455 - 456
Database
ISI
SICI code
0022-4936(1995):4<455:FO[WA->2.0.ZU;2-A
Abstract
In reactions between the hexamolybdate [Mo6O19](2-) and 1,4-diaminoben zene, terminal oxides are replaced by 4-aminophenylimido ligands and t he first structurally characterised polyoxometallate to contain functi onalised organoimido ligands, ((BU4N)-N-n)(2)[Mo6O17(NC6H4NH2)(2)] 5, is also the first example of a trans-bis(imido) derivative; further co ndensation also occurs to yield species in which hexamolybdate units a re linked by 1,4-phenylenediimido bridges.