THE PALLADIUM(II) COORDINATION CHEMISTRY OF FERROCENYLPHOSPHINOBIPYRIDINES - A NOVEL TRANS-CHELATING LIGAND SYSTEM

Authors
BUTLER IR KALAJI M NEHRLICH L HURSTHOUSE M KARAULOV AI MALIK KMA
Citation
Ir. Butler et al., THE PALLADIUM(II) COORDINATION CHEMISTRY OF FERROCENYLPHOSPHINOBIPYRIDINES - A NOVEL TRANS-CHELATING LIGAND SYSTEM, Journal of the Chemical Society, Chemical Communications, (4), 1995, pp. 459-460
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
4
Year of publication
1995
Pages
459 - 460
Database
ISI
SICI code
0022-4936(1995):4<459:TPCCOF>2.0.ZU;2-C
Abstract
The reaction of dichloro(cycloocta-1,5-diene)palladium(II) with 1-diph enyl-(L(1)) or -butyl)-phosphino-1'-[6-(2,2'-bipyridyl)]ferrocene (L(2 )) results in the novel trans-coordination geometry with the beta-pyri dinyl ring and the phosphine group binding to the,metal centre, as pro ved by a crystal structure determination of [PdCl(2)L(1)][PdCl2(cod)].