HETEROLYTIC C-O CLEAVAGE IN ARYLETHERS ACTIVATED BY [FE(ETA(5)-C5H5)](+)

Authors
MOULINES F DJAKOVITCH L DELVILLEDESBOIS MH ROBERT F GOUZERH P ASTRUC D
Citation
F. Moulines et al., HETEROLYTIC C-O CLEAVAGE IN ARYLETHERS ACTIVATED BY [FE(ETA(5)-C5H5)](+), Journal of the Chemical Society, Chemical Communications, (4), 1995, pp. 463-464
Citations number
21
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
4
Year of publication
1995
Pages
463 - 464
Database
ISI
SICI code
0022-4936(1995):4<463:HCCIAA>2.0.ZU;2-3
Abstract
The C-O bond of Fe(eta(5)-C5H5)(+) complexes of aryl ethers is cleaved smoothly by reaction of Bu(t)OK in THF or KOH in DME, yielding pi-phe nate complexes; transetherification can also be achieved in situ at ro om temperature.