COPPER-DIOXYGEN REACTIVITY INVOLVED IN THE FORMATION OF MU-OXO [(POR)FE-III-O-CU(III)L](-PLANAR FE-II(POR) SPECIES() HETERODINUCLEAR COMPLEXES (POR=PORPHYRINATE, L=TETRADENTATE LIGAND), AND NOVEL SYNTHESIS OF SQUARE)

Authors
NANTHAKUMAR A FOX S KARLIN KD
Citation
A. Nanthakumar et al., COPPER-DIOXYGEN REACTIVITY INVOLVED IN THE FORMATION OF MU-OXO [(POR)FE-III-O-CU(III)L](-PLANAR FE-II(POR) SPECIES() HETERODINUCLEAR COMPLEXES (POR=PORPHYRINATE, L=TETRADENTATE LIGAND), AND NOVEL SYNTHESIS OF SQUARE), Journal of the Chemical Society, Chemical Communications, (4), 1995, pp. 499-501
Citations number
16
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
4
Year of publication
1995
Pages
499 - 501
Database
ISI
SICI code
0022-4936(1995):4<499:CRIITF>2.0.ZU;2-J
Abstract
In the reaction of Fe-II(por) species with [LCu(I)(MeCN)](+) and O-2 t o give mu-oxo [(por)Fe-III-O-Cu(II)L](+) 3 (per = porphyrinate, L = te tradentate ligand), copper-dioxygen adducts or their decomposition pro ducts must be present, otherwise [(por)Fe-III-OH] or [(por)Fe-III-O-Fe -III(por)] products appear; a novel synthesis of square-planar Fe-II(p or) is also described.