CIS-TRANS ISOMERIC INFLUENCE ON THE REACTIVITY OF BRMN(CO)(2)DPPMP(OPH)(3) TOWARDS DIALKYLTHIOETHERS

Authors
DIAZ C LEAL C
Citation
C. Diaz et C. Leal, CIS-TRANS ISOMERIC INFLUENCE ON THE REACTIVITY OF BRMN(CO)(2)DPPMP(OPH)(3) TOWARDS DIALKYLTHIOETHERS, Polyhedron, 14(3), 1995, pp. 425-428
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
14
Issue
3
Year of publication
1995
Pages
425 - 428
Database
ISI
SICI code
0277-5387(1995)14:3<425:CIIOTR>2.0.ZU;2-9
Abstract
Trans-[BrMn(CO)(2)(dppm)P(OPh)(3)] reacts with SR(2); R = C2H5 and C3H 7 to give the cationic complexes trans-[Mn(CO)(2)(dppm)P(OPh)(3)(SR(2) )]PF6 while from the reaction of cis,cis [BrMn(CO)(2)(dppm)P(OPh)(3)] with the thioether ligands the unaltered dicarbonyl manganese complex was isolated. The new cationic complexes were characterized by element al analysis, IR, H-1-NMR, P-31-NMR and UV-visible spectroscopic method s. The different reactivity between the cis and trans isomers is discu ssed in terms of Mn-Br bond strength and steric factors.