A BINUCLEAR NICKEL(II) COMPLEX CONTAINING AN OXAMIDO-BRIDGE - SYNTHESIS, PROPERTIES AND X-RAY CRYSTAL-STRUCTURE OF [NI(OXAE)NI(PHEN)(2)](CLO4)(2)CENTER-DOT-3H2O

Authors
WEI PR JIA L LIU CR HAN Q WEI GC GAO S
Citation
Pr. Wei et al., A BINUCLEAR NICKEL(II) COMPLEX CONTAINING AN OXAMIDO-BRIDGE - SYNTHESIS, PROPERTIES AND X-RAY CRYSTAL-STRUCTURE OF [NI(OXAE)NI(PHEN)(2)](CLO4)(2)CENTER-DOT-3H2O, Polyhedron, 14(3), 1995, pp. 441-444
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
14
Issue
3
Year of publication
1995
Pages
441 - 444
Database
ISI
SICI code
0277-5387(1995)14:3<441:ABNCCA>2.0.ZU;2-I
Abstract
The binuclear complex [Ni(oxae)Ni(phen)2](ClO4)(2) . H2O (oxae=N,N'bis (2-aminoethyl) oxamido dianion, phen = 1, 10-phenanthroline) was prepa red from the planar monomeric complex Ni(oxae) and characterized throu gh analytical and spectroscopic measurements. The structure of [Ni(oxa e)Ni(phen)(2)] (ClO4)2 . 3H(2)O was investigated by single-crystal X-r ay analysis. The complex has an extended oxamido-bridged structure and consists of two nickel(II) ions, one of them in a square planar envir onment and another in a distorted octahedral environment. The Ni-Ni di stance is 5.267 Angstrom.