NEW ROUTES FOR THE SYNTHESIS OF CHLORO(DIETHYLENETRIAMINE)PLATINUM(II)CHLORIDE AND CHLORO(2,2' 6',2''-TERPYRIDINE)PLATINUM(II) CHLORIDE DIHYDRATE/

Authors
ANNIBALE G BRANDOLISIO M PITTERI B
Citation
G. Annibale et al., NEW ROUTES FOR THE SYNTHESIS OF CHLORO(DIETHYLENETRIAMINE)PLATINUM(II)CHLORIDE AND CHLORO(2,2' 6',2''-TERPYRIDINE)PLATINUM(II) CHLORIDE DIHYDRATE/, Polyhedron, 14(3), 1995, pp. 451-453
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
14
Issue
3
Year of publication
1995
Pages
451 - 453
Database
ISI
SICI code
0277-5387(1995)14:3<451:NRFTSO>2.0.ZU;2-1
Abstract
[Pt(dien)Cl]Cl (dien = diethylenetriamine) has been obtained in high y ield (> 90%) by interaction of cis-[Pt(dmso)(2)Cl-2] (dmso = dimethyls ulfoxide) with the triamine in methanol. The same method, when applied to 2,2': 6',2 ''-terpyridine (terpy), gave a mixture of [Pt(terpy)Cl] [Pt(dmso)Cl-3] and [Pt(terpy)Cl]Cl . 2H(2)O. The latter complex has b een obtained in nearly quantitative yield by interaction of equimolar amounts of[Pt(COD)Cl-2] (COD = 1,5-cyclooctadiene) and terpy in water.