We measured the ac conductivity of polycrystalline FeSi at temperature
s 80 mK less than or equal to T less than or equal to 450 K and freque
ncies 20 Hz less than or equal to nu less than or equal to 1 GHz. At t
emperatures T < 25 K the ac response is governed by hopping of localiz
ed charge carriers. However, the complex conductivity in FeSi cannot b
e described by models developed for conventional semiconductors. At hi
gher temperatures no signs of hopping conductivity could be found. Obv
iously itinerant charge carriers dominate the charge transport for T >
25 K and deviations of the temperature dependence of the de resistivi
ty from a thermally activated behavior which occur below 90 K are not
due to Anderson localization but probably to Kondo-like behavior. Belo
w 4 K the dielectric constant increases by an order of magnitude signa
ling a reentrant transition into a metallic state.