CRYSTAL SOLVATE OF C-60 WITH TRICLOROETHYLENE, C-60-CENTER-DOT-C2HCL3

Authors
GRITSENKO VV DYACHENKO OA KUSHCH ND SPITSINA NG YAGUBSKII EB AVRAMENKO NV FROLOVA MN
Citation
Vv. Gritsenko et al., CRYSTAL SOLVATE OF C-60 WITH TRICLOROETHYLENE, C-60-CENTER-DOT-C2HCL3, Russian chemical bulletin, 43(7), 1994, pp. 1183-1185
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
43
Issue
7
Year of publication
1994
Pages
1183 - 1185
Database
ISI
SICI code
1066-5285(1994)43:7<1183:CSOCWT>2.0.ZU;2-Q
Abstract
Extraction of fullerenes from carbon soot by trichloroethylene has bee n studied. We have found that C-60 forms a solvate with trichloroethyl ene (C-60.C2HCl3: a = 31.31(1); b = 10.156(4); c = 10.146(4) Angstrom; V = 3228.6 Angstrom(3), Z = 4, d(calc), = 1.752 g cm(-3), orthorhombi c symmetry). Its thermal stability has been studied using TG and DSC. A phase transition of the first order at 167 K has been detected.