SYNTHESIS OF DIASTEREOMERIC 1,2-DISUBSTITUTED FERROCENES OF HIGH OPTICAL PURITY FROM RACEMIC ALPHA-DIMETHYLAMINOALKYLFERROCENES

Authors
TROITSKAYA LL BULYGINA LA SOKOLOV VI
Citation
Ll. Troitskaya et al., SYNTHESIS OF DIASTEREOMERIC 1,2-DISUBSTITUTED FERROCENES OF HIGH OPTICAL PURITY FROM RACEMIC ALPHA-DIMETHYLAMINOALKYLFERROCENES, Russian chemical bulletin, 43(7), 1994, pp. 1253-1259
Citations number
8
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
43
Issue
7
Year of publication
1994
Pages
1253 - 1259
Database
ISI
SICI code
1066-5285(1994)43:7<1253:SOD1FO>2.0.ZU;2-W
Abstract
A novel approach to the synthesis of optically active 1,2-bifunctional ferrocenes of high optical purity with any combination of absolute co nfigurations of the chiral center and the chiral plane has been propos ed. The method is based on asymmetric cyclopalladation of racemic alph a-dimethylaminoethylferrocene under the conditions of its kinetic reso lution.