AURATION OF RUTHENOCENE - SYNTHESIS AND MOLECULAR-STRUCTURE OF MONOAURATED AND DIAURATED DERIVATIVES

Authors
NEFEDOVA MN MAMEDYAROVA IA SOKOLOV VI SMYSLOVA EI KUZMINA LG GRANDBERG KI
Citation
Mn. Nefedova et al., AURATION OF RUTHENOCENE - SYNTHESIS AND MOLECULAR-STRUCTURE OF MONOAURATED AND DIAURATED DERIVATIVES, Russian chemical bulletin, 43(7), 1994, pp. 1275-1277
Citations number
5
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
43
Issue
7
Year of publication
1994
Pages
1275 - 1277
Database
ISI
SICI code
1066-5285(1994)43:7<1275:AOR-SA>2.0.ZU;2-Q
Abstract
Ruthenocene, like ferrocene, reacts with (Ph(3)PAu)(3)O+BF4- to afford a gem-diaurated derivative CpRuC(5)H(4)(AuPPh(3))(2) (BF4-)-B-+, whic h is converted into CpRuC(5)H(4)AuPPh(3) when treated with PPh(3). X-r ay structural analysis revealed substantial Ru-Au interaction in the d iaurated derivative.