NON-EQUILIBRATION OF THE [M-H](-) IONS OF ISOMERIC DIMETHYLSULFONE AND METHYL METHYLSULPHINATE

Authors
DUA S BOWIE JH
Citation
S. Dua et Jh. Bowie, NON-EQUILIBRATION OF THE [M-H](-) IONS OF ISOMERIC DIMETHYLSULFONE AND METHYL METHYLSULPHINATE, Rapid communications in mass spectrometry, 9(2), 1995, pp. 175-176
Citations number
16
Categorie Soggetti
Spectroscopy,"Chemistry Analytical
Journal title
Rapid communications in mass spectrometry → ACNP
ISSN journal
09514198
Volume
9
Issue
2
Year of publication
1995
Pages
175 - 176
Database
ISI
SICI code
0951-4198(1995)9:2<175:NOT[IO>2.0.ZU;2-2
Abstract
The collision-induced dissociations of (CH2S)-C--(O)(2)CH3, (CD2S)-C-- (O)(2)CH3 and (CH2S)-C--(O)OCH3 indicate that (i) a sulphone/sulphinat e ester rearrangement does not occur for these systems, (ii) proton tr ansfer accompanying or preceding the fragmentation of the [M-H](-) ion of the sulphone is a minor process, and (iii) the characteristic frag mentations of (CH2S)-C--(O)(2)CH3 and (CH2S)-C--(O)OCH3 form [CH2S(O)( 2)](-.) and HCSO- respectively.