ACTIVATED CARBON FOR CONTROL OF NITROGEN-OXIDE EMISSIONS

Activated carbons were used to selectively remove NOx from simulated f lue gas at temperatures between 25 and 125 degrees C. Processing condi tions and physical/chemical characteristics of the carbons which affec ted NOx adsorption, storage, and release were investigated. Oxygen as a coreactant was necessary to maximize the conversion of NO to NO2 and condensation of NO2 within the pores of the carbons. A NO-to-NO2 conv ersion mechanism is presented and discussed relative to previous resea rch. A process for selectively removing NOx and concentrating it as NO 2 in an alternate process stream is outlined. The purified NO2 stream could be used far chemicals manufacturing.