INVESTIGATIONS OF THE INTERFACE BETWEEN MAGNESIUM AND POLYETHYLENETEREPHTHALATE BY X-RAY PHOTOELECTRON-SPECTROSCOPY

The interfacial chemistry between in-situ thermally evaporated magnesi um and a polyethyleneterephthalate (PET) film is studied by X-ray phot oelectron spectroscopy (XPS). The initially deposited Mg atoms adsorb on the PET surface, via an addition reaction to the C=O groups, with t he simultaneous formation of Mg-O and Mg-C bonds. Further metallizatio n shows condensation in the agglomeration mode, with metallic clusters formed by adsorption on to the initial Mg at the PET interface. With exposure of the Mg/PET film to air, the interface does not change alth ough the outer metallic component oxidizes. Rinsing this air-oxidized Mg/PET film with water removes all the magnesium and leaves a modified PET surface compared with its initial state.