CAPILLARY WAVES AT THE LIQUID-VAPOR INTERFACE - WIDOM-ROWLINSON MODELAT LOW-TEMPERATURE

Citation
Fh. Stillinger et Jd. Weeks, CAPILLARY WAVES AT THE LIQUID-VAPOR INTERFACE - WIDOM-ROWLINSON MODELAT LOW-TEMPERATURE, Journal of physical chemistry, 99(9), 1995, pp. 2807-2816
Citations number
34
Categorie Soggetti
Chemistry Physical
ISSN journal
00223654
Volume
99
Issue
9
Year of publication
1995
Pages
2807 - 2816
Database
ISI
SICI code
0022-3654(1995)99:9<2807:CWATLI>2.0.ZU;2-G
Abstract
We have examined in detail the structure and properties of the liquid- vapor interface for the two-dimensional Widom-Rowlinson model in its l ow-temperature regime. Various simplifying features permit the deducti on of several basic results. Included among these are (1) unambiguous definition of capillary wave modes with upper wavelength cutoff propor tional to rho(1)(-1/3) (rho(1) = liquid density); (2) wavelength dispe rsion of bare surface tension; and (3) nonmonotonic intrinsic density profile (i.e., that with vanishing capillary wave amplitudes). In an A ppendix we show how many of these results can be extended to the three and higher dimensional cases.