Mm. Taylor et al., EFFECT OF VARIOUS ALKALINITY-INDUCING AGENTS ON CHEMICAL AND PHYSICAL-PROPERTIES OF PROTEIN PRODUCTS ISOLATED FROM CHROMIUM-CONTAINING LEATHER WASTE, The Journal of the American Leather Chemists Association, 89(7), 1994, pp. 221-228
We have demonstrated that gelable and hydrolyzed protein products can
be obtained from chromium-containing leather waste. Depending on the c
hoice of alkalinity-inducing agent added, products with varying chemic
al and physical properties can be isolated. Also, we have shown that t
he ash content of these isolated protein products will be dependent no
t only on the choice of alkalinity-inducing agent, but also on the che
mical make-up of the original substrate. One of the components of the
ash is chromium and its content is also influenced by the choice of al
kalinity-inducing agent. We found that adding magnesium oxide in combi
nation with sodium or potassium hydroxide increases the chromium conte
nt in the gelable protein products over that obtained with magnesium o
xide alone. Substituting carbonate salts for sodium or potassium hydro
xide lowers the chromium content of the gelable protein products. Choi
ce of alkalinity-inducing agent has little effect on the chromium cont
ent of the hydrolyzed protein products. With respect to Bloom value an
d viscosity of the gelable protein products, magnesium oxide alone giv
es the superior product, whereas the introduction of carbonates and hy
droxides has a detrimental effect. Hydroxide is more detrimental than
carbonate. In this study we have shown that a variety of products can
be isolated with varying properties and these properties will be depen
dent on the desired end use of the protein product.