The results of a numerical study aimed to verify the accuracy of the t
hermodynamic models based on the Boltzmann distribution in the hyperso
nic regime and to detect discrepancies, if any, with the analysis base
d on the more rigorous method of vibrational kinetics are presented an
d discussed. The test case considered in the study is the steady, two-
dimensional, chemically inert, inviscid flow of diatomic nitrogen past
an infinite cylinder in a uniform stream at M(x) = 6.5. The vibration
al relaxation has been calculated from the standard vibrational energy
rate equation, assuming a harmonic-oscillator behavior of N-2, and fr
om a set of vibrational master equations that account for the first 10
vibrational energy levels of the N-2 molecule, assumed as an anharmon
ic oscillator. The now patterns produced by the two calculation method
s are thoroughly discussed and the critical: influence of the vibratio
nal relaxation time, associated with the harmonic-oscillator models, i
n determining agreement or disagreement with the results from the vibr
ational kinetics method is evidenced.