A FACILE GENERATION OF ORGANOSAMARIUM ETA(3)-ALLYL COMPLEXES BY REDUCTIVE CLEAVAGE OF ALLYLIC ETHERS WITH (C(5)ME(5))(2)SM(THF)(N)

Authors
TAKAKI K KUSUDO T UEBORI S MAKIOKA Y TANIGUCHI Y FUJIWARA Y
Citation
K. Takaki et al., A FACILE GENERATION OF ORGANOSAMARIUM ETA(3)-ALLYL COMPLEXES BY REDUCTIVE CLEAVAGE OF ALLYLIC ETHERS WITH (C(5)ME(5))(2)SM(THF)(N), Tetrahedron letters, 36(9), 1995, pp. 1505-1508
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
9
Year of publication
1995
Pages
1505 - 1508
Database
ISI
SICI code
0040-4039(1995)36:9<1505:AFGOOE>2.0.ZU;2-#
Abstract
Reductive C-O bond cleavage of allylic benzyl ethers with two equivale nts of (C(5)Me(5))(2)Sm(THF)(n) (n=2 or 0) takes place selectively to generate (C(5)Me(5))(2)Sm(eta(3)-allyl) complexes in high yields along with equimolar amounts of the samarium benzyloxide.