INFLUENCE OF METHACRYLIC-ACID DIMERIZATION ON THE CONFIGURATIONAL ANDCOMPOSITIONAL TRIAD SEQUENCES IN METHACRYLIC-ACID METHYL-METHACRYLATECOPOLYMERS

Authors
GEORGIEV GS DAKOVA IG
Citation
Gs. Georgiev et Ig. Dakova, INFLUENCE OF METHACRYLIC-ACID DIMERIZATION ON THE CONFIGURATIONAL ANDCOMPOSITIONAL TRIAD SEQUENCES IN METHACRYLIC-ACID METHYL-METHACRYLATECOPOLYMERS, European Polymer Journal, 31(3), 1995, pp. 305-307
Citations number
6
Categorie Soggetti
Polymer Sciences
Journal title
European Polymer Journal → ACNP
ISSN journal
00143057
Volume
31
Issue
3
Year of publication
1995
Pages
305 - 307
Database
ISI
SICI code
0014-3057(1995)31:3<305:IOMDOT>2.0.ZU;2-J
Abstract
The influence of methacrylic acid (A) dimerization in toluene on its c opolymerization with methyl methacrylate (B) was studied. it was estab lished that as a result of this influence the dependence of the config urational triad mole fraction on the monomer feed is non-linear, r(A)= 1.05+/-0.03, r(B)=0.05+/-0.02 and the experimental values of the alter nating ABA and BAB compositional triads are rather smaller than those calculated by the terminal model which does not take account of the di mer participation in the chain propagation.