EFFICIENT SYNTHESIS OF POLYPRENYL DIPHOSP HATES

Authors
MALTSEV SD TRIFONOV AV DANILOV LL SHIBAEV VN
Citation
Sd. Maltsev et al., EFFICIENT SYNTHESIS OF POLYPRENYL DIPHOSP HATES, Bioorganiceskaa himia, 21(1), 1995, pp. 61-65
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Bioorganiceskaa himia → ACNP
ISSN journal
01323423
Volume
21
Issue
1
Year of publication
1995
Pages
61 - 65
Database
ISI
SICI code
0132-3423(1995)21:1<61:ESOPDH>2.0.ZU;2-Q
Abstract
Efficient synthesis of polyprenyl diphosphates from the corresponding monophosphates by the diphenylpyrophosphate approach has been develope d. The method was applied to various polyprenols with the alpha-termin al isoprene (Z- or E-) or alpha-dihydroisoprene units. Moraprenyl diph osphate was also synthesized by interaction of moraprenyl phosphoroimi dazolidate with 2-cyanoethyl phosphate followed by elimination of cyan oethyl group under basic conditions.