P-H-FUNCTIONALIZED ZIRCONOCENE PHOSPHIDO COMPLEXES - SYNTHESIS OF CP'ZR-2(PH(2,4,6-(PR3C6H2)-C-I))(X) (CP'=C(5)H(4)ME, X=CL, 2,4,6-(PR3C6H2)-C-I) AND MOLECULAR-STRUCTURE OF CP'2ZRCL(PH(2,4,6-(PR3C6H2)-C-I))

Authors
HEYHAWKINS E KURZ S BAUM G
Citation
E. Heyhawkins et al., P-H-FUNCTIONALIZED ZIRCONOCENE PHOSPHIDO COMPLEXES - SYNTHESIS OF CP'ZR-2(PH(2,4,6-(PR3C6H2)-C-I))(X) (CP'=C(5)H(4)ME, X=CL, 2,4,6-(PR3C6H2)-C-I) AND MOLECULAR-STRUCTURE OF CP'2ZRCL(PH(2,4,6-(PR3C6H2)-C-I)), Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 50(2), 1995, pp. 239-242
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur Naturforschung. B, A journal of chemical sciences → ACNP
ISSN journal
09320776
Volume
50
Issue
2
Year of publication
1995
Pages
239 - 242
Database
ISI
SICI code
0932-0776(1995)50:2<239:PZPC-S>2.0.ZU;2-2
Abstract
The reaction of Cp'2ZrCl2 (Cp' = C(5)H(4)Me) with solvent-free LiPH(2, 4,6-(Pr3C6H2)-C-i) yields the terminal zirconocene phosphido complexes Cp'2ZrCl{PH(2,4,6-(Pr3C6H2)-C-i)} (1) (1:1 reaction) or Cp'Zr-2{PH(2, 4,6-(Pr3C6H2)-C-i)}(2) (2) (1:2 reaction). 1 and 2 were characterized spectroscopically (NMR, IR, MS). An X-ray structure determination was carried out on 1 (Zr-P 2.6381(8) Angstrom, Zr-Cl 2.4547(6) Angstrom, C l-Zr-P 93.55(2)degrees).