TRIFLUOROMETHYL-SUBSTITUTED GERMANIUM HET EROCYCLES VIA [4+1] CYCLOADDITION REACTIONS

Authors
KARSCH HH BIENLEIN F HECKEL M STEIGELMANN O BURGER K CYRENER J
Citation
Hh. Karsch et al., TRIFLUOROMETHYL-SUBSTITUTED GERMANIUM HET EROCYCLES VIA [4+1] CYCLOADDITION REACTIONS, Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 50(2), 1995, pp. 289-293
Citations number
55
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur Naturforschung. B, A journal of chemical sciences → ACNP
ISSN journal
09320776
Volume
50
Issue
2
Year of publication
1995
Pages
289 - 293
Database
ISI
SICI code
0932-0776(1995)50:2<289:TGHEV[>2.0.ZU;2-K
Abstract
Formation of partially fluorinated imidazoles 6 from 4,4-bis(trifluoro methyl)-1,3-diazabuta-1,3-dienes 1 in the presence of low-valent metal compounds is shown to proceed via a [4+1] cycloadduct in the case of germanium(II)-chloride. The resulting germole 3 has been characterized by X-ray analysis. The five-membered ring is planar and the germanium atom adopts tetrahedral configuration.